Oxetane Synthesis: Methyl Vinyl Sulphides as New Traps of Excited Benzophenone in a Stereoselective and Regiospecific Paterno-Buechi Reaction

DOI: 10.1039/c39870000964

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 964 - 965 (1987)

Update date:2022-07-31

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Authors:

Morris, Trevor H.

Smith, Edward H.

Walsh, Roger

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Article abstract of DOI:10.1039/c39870000964

The almost exclusive products in the photochemical addition of benzophenone to methyl vinyl sulphides are the 3-methylthio-oxetanes, formed with selectivity for the trans-4-alkyl-3-methylthio configuration, as shown by an X-ray crystal structure determination and difference nuclear Overhauser effects studies.

Full text of DOI:10.1039/c39870000964

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