Oxetane Synthesis: Methyl Vinyl Sulphides as New Traps of Excited Benzophenone in a Stereoselective and Regiospecific Paterno-Buechi Reaction

DOI: 10.1039/c39870000964

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 964 - 965 (1987)

Update date:2022-07-31

Topics:

Authors:

Morris, Trevor H.

Smith, Edward H.

Walsh, Roger

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870000964

The almost exclusive products in the photochemical addition of benzophenone to methyl vinyl sulphides are the 3-methylthio-oxetanes, formed with selectivity for the trans-4-alkyl-3-methylthio configuration, as shown by an X-ray crystal structure determination and difference nuclear Overhauser effects studies.

Full text of DOI:10.1039/c39870000964

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:4-isopropyl-3-methyl-3-methylthio-2,2-diphenyloxetane

Cas No:113119-11-2

R&D Labs maybe for 113119-11-2

Tianjin Crest Pharmaceutical R&D Co., Ltd. （Tianjin Yao Technology Development Co., Ltd.）(expird)

Contact:+86-22-66211386

Address:Building B5-405, No, 80 4th Avenue, TEDA, Tianjin, China P.R. 300457
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Henan Yellow River New Material Technology Co.Ltd.

website:http://www.yellowriverchem.com

Contact:0086-373-7278760

Address:Chengguan Town, Yuanyang County
Xi'an yuanfar international trade company

website:https://www.yuanfarchemical.com

Contact:86-029-88745613 ext 828

Address:Floor19th ,B Building, Oak Block,No.36 South Fenghui Road, Dev. Zone of High-Tech Ind.,Xi’an, China
Changzhou Anyi Biochem Co., Ltd.(expird)

Contact:+86-519-88836158

Address:no,51 caoda

Relevant to this article

One-pot and sequential organic chemistry on an enzyme surface to tether a fluorescent probe at the proximity of the active site with restoring enzyme activity

Doi:10.1021/ja057926x
(2006)
Investigation of mechanism-based thrombin inhibitors: Implications of a highly conserved water molecule for the binding of coumarins within the S pocket

Doi:10.1016/j.bmcl.2005.12.070
(2006)
Cycloaddition chemistry of 1,3-thiazolium-4-olate systems. Reaction with nitroalkenes and interpretation of results using PM3 calculations

Doi:10.1021/jo952275g
(1996)
A NEW ONE-POT METHOD FOR α,α-DIALLYLATION OF KETONES BASED ON THE PALLADIUM-CATALYZED REACTION OF ALLYLIC CARBONATES AND ALLYL β-KETO CARBOXYLATES UNDER NEUTRAL CONDITIONS

Doi:10.1016/S0040-4039(00)94297-7
(1983)
Preparation of Fluorine-Containing Phenylacetylenes by the Method of Introduction of the Ethynyl Group Using 1,1-Dichloro-2,2-difluroethene

Doi:10.1246/bcsj.61.1625
(1988)
Total synthesis of (-)-xyloketal A

Doi:10.1021/ol060266w
(2006)

Article Doi