Synthesis p. 551 - 554 (1987)
Update date:2022-08-03
Evans, Robert D.
Schauble, J. Herman
I(+)(Collidine)2BF4(-) in dichloromethane has been found to be a convenient reagent for regio- and stereospecific conversion of a variety of cycloalkenes to vicinal trans-iodofluorocycloalkanes.With bicyclo<2.2.1>heptene and bicyclo<2.2.1>heptadiene, only tricyclic products were obtained.Application of the title reagent to certain glycal esters provides a new method for stereoselective synthesis of trans-diaxial iodopyranosyl fluorides.
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(2016)Doi:10.1007/BF00772855
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(1992)
