PALLADIUM CATALYZED DOUBLE SILYLATION OF BIS(TRIMETHYLSILYL)BUTADIYNE BY MEANS OF DISILANES

DOI: 10.1016/S0040-4039(00)95427-3

Source and publish data:

Tetrahedron Letters p. 1807 - 1810 (1987)

Update date:2022-07-29

Topics:

Authors:

Kusumoto, Tetsuo

Hiyama, Tamejiro

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Article abstract of DOI:10.1016/S0040-4039(00)95427-3

Reaction of bis(trimethylsilyl)butadiyne with Si₂Cl_xMe_6-x in the presence of a palladium catalyst gives, after methylation, 1,1,4,4-tetrakis(trimethylsilyl)butatriene and/or 1,1,2,4-tetrakis(trimethylsilyl)-1-buten-3-yne s

Full text of DOI:10.1016/S0040-4039(00)95427-3

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