FORMATION ET REACTIVITE DES CARBANIONS BENCHROTRENIQUES DANS LE THF. ADDITION D'OXALATE D'ETHYLE ET DE BENZALDEHYDE, EVOLUTION DES PRODUITS D'ADDITION PAR OXYDATION D'OPPENAUER-WOODWARD

DOI: 10.1016/0022-328X(85)80211-4

Source and publish data:

Journal of Organometallic Chemistry p. C5 - C8 (1985)

Update date:2022-08-03

Topics:

Authors:

Senechal-Tocquer, M.-C.

Senechal, D.

Bihan, J-Y. Le

Gentric, D.

Caro, B.

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Article abstract of DOI:10.1016/0022-328X(85)80211-4

Aromatic hydrocarbons complexed by a Cr(CO)3 unit react in THF and in the presence of t-BuOK, at the benzylic position with (COOEt)2 and PhCHO to give good yields of condensation products.With PhCHO formation of ketone via in situ Oppenauer-Woodward oxidation, is observed.

Full text of DOI:10.1016/0022-328X(85)80211-4

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Product name:C₆H₅CH(C₂H₅)CH(OH)C₆H₅Cr(CO)3

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