Influence of hydroxylamine conformation on stereocontrol in Pd-catalyzed isoxazolidine-forming reactions

DOI: 10.1021/jo8027399

Source and publish data:

Journal of Organic Chemistry p. 2533 - 2540 (2009)

Update date:2022-08-04

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Authors:

Lernen, Georgia S.

Giampietro, Natalie C.

Hay, Michael B.

Wolfe, John P.

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Article abstract of DOI:10.1021/jo8027399

Palladium-catalyzed carboamination reactions between N-Boc-O-(but-3-enyl) hydroxylamine derivatives and aryl or alkenyl bromides afford cis-3,5- and trans-4,5-disubstituted isoxazolidines in good yield with up to >20:1 dr. The diastereoselectivity observe

Full text of DOI:10.1021/jo8027399

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