Journal of the Chemical Society. Perkin transactions I p. 865 - 866 (1996)
Update date:2022-08-05
Topics:
Fujii, Nobutaka
Habashita, Hiromu
Akaji, Masako
Nakai, Kazuo
Ibuka, Toshiro
Fujiwara, Masahiro
Tamamura, Hirokazu
Yamamoto, Yoshinori
A simple synthetic method for the preparation of scalemic allylic alcohols from toluene-p-sulfonates of scalemic 2,3-epoxy alcohols is reported. Satisfactory yields are obtained by treatment of toluene-p-sulfonates of 2,3-epoxy alcohols with potassium iodide followed by triphenylphosphine and iodine in a one-pot synthesis.
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