SYNTHESE DE VINYLIDENE-3 PYRROLIDINES, PIPERIDINES ET PERHYDROAZEPINES A PARTIR D'ω-MONOALKYLAMINOPROPARGYLTRIMETHYLSILANES PAR PROCESSUS D'AMINOMETHYLATION-DESILYLATION INTRAMOLECULAIRE

DOI: 10.1016/S0040-4039(00)96598-5

Source and publish data:

Tetrahedron Letters p. 4689 - 4690 (1987)

Update date:2022-09-26

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Authors:

Damour, D.

Pornet, J.

Miginiac, L.

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Article abstract of DOI:10.1016/S0040-4039(00)96598-5

In acidic medium, the ω-monoalkylaminopropargyltrimethylsilanes regiospecifically reacted with formaldehyde, affording 3-vinylidene nitrogen-containing heterocycles, such as 3-vinylidene pyrrolidines, piperidines and perhydroazepines.

Full text of DOI:10.1016/S0040-4039(00)96598-5

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