
Tetrahedron Letters p. 4787 - 4790 (1986)
Update date:2022-08-03
Topics:
Paterson, Ian
Lister, M. Anne
McClure, Cynthia K.
Aldol condensation between diethylketone and simple aldehydes using (Ipc)2BOTf/iPr2NEt in CH2Cl2 gives syn adducts in good ee (66-90percent) and with high diastereoselectivity (>=90percent).Other chiral dialkylboron triflate reagents examined give lower ees.
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