N-BENZENE-SULFONYL-INDOLE AS TERMINATOR IN A BIOMIMETIC POLYENE CYCLIZATION: SYNTHESIS OF A PENTACYCLIC INDOLOSESQUITERPENE

DOI: 10.1016/S0040-4039(00)95537-0

Source and publish data:

Tetrahedron Letters p. 3565 - 3568 (1987)

Update date:2022-07-30

Topics:

Authors:

Mirand, Catherine

Maindreville, Michele Doee de

Cartier, Dominique

Levy, Jean

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Article abstract of DOI:10.1016/S0040-4039(00)95537-0

Epoxide 14 was cyclized with BF3 to the pentacyclic derivative 17, which was further elaborated to 19, a stereoisomer of the natural indolosesquiterpene polyveoline.

Full text of DOI:10.1016/S0040-4039(00)95537-0

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