N-BENZENE-SULFONYL-INDOLE AS TERMINATOR IN A BIOMIMETIC POLYENE CYCLIZATION: SYNTHESIS OF A PENTACYCLIC INDOLOSESQUITERPENE

DOI: 10.1016/S0040-4039(00)95537-0

Source and publish data:

Tetrahedron Letters p. 3565 - 3568 (1987)

Update date:2022-07-30

Topics:

Authors:

Mirand, Catherine

Maindreville, Michele Doee de

Cartier, Dominique

Levy, Jean

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)95537-0

Epoxide 14 was cyclized with BF3 to the pentacyclic derivative 17, which was further elaborated to 19, a stereoisomer of the natural indolosesquiterpene polyveoline.

Full text of DOI:10.1016/S0040-4039(00)95537-0

Products guided by the article

Product name:1H-Indole, 1-(phenylsulfonyl)-2-(3,7,11-trimethyl-2,6,10-dodecatrienyl)-, (E,E)-

Cas No:113801-51-7

R&D Labs maybe for 113801-51-7

Tianjin Crest Pharmaceutical R&D Co., Ltd. （Tianjin Yao Technology Development Co., Ltd.）(expird)

Contact:+86-22-66211386

Address:Building B5-405, No, 80 4th Avenue, TEDA, Tianjin, China P.R. 300457
Liaoyang Xinyou Chemical Products Co.,Ltd.

Contact:+86-419-5165433 13604191870

Address:Huishang Road6-1, Hongwei District, Liaoyang, Liaoning, China
Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
BAODING SINO-CHEM INDUSTRY CO.,LTD

Contact:0312-5956088

Address:NO.8 FUXING ROAD,CHINA
JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing

Relevant to this article

An Easy Route to Dibenzazepines via Nitrile Ylide Cyclisation: the Electrocyclic Equivalent of a Bischler-Napieralski Reaction

Doi:10.1039/c39870001367
(1987)
One-pot synthesis of β-amido ketones using bronsted acidic ionic liquid as an efficient and reusable catalyst

Doi:10.1139/V08-173
(2009)
An efficient method for the synthesis of α-arylated nitroalkanes and α-arylated hydroximoyl chlorides mediated by AlCl₃

Doi:10.1016/j.tet.2009.01.075
(2009)
Palladium-Catalyzed Aminomethylation and Cyclization of Enynol to O-Heterocycle Confined 1,3-Dienes

Doi:10.1021/acs.orglett.1c01019
(2021)
N,N,N′,N′-Tetraalkyl-2,2′-dihydroxy-1,1′- binaphthyl-3,3′-dicarboxamides: Novel Chiral Auxiliaries for Asymmetric Simons-Smith Cyclopropanation of Allylic Alcohols and for Asymmetric Diethylzinc Addition to Aldehydes

Doi:10.1246/bcsj.70.207
(1997)
Enantiopure N-protected α-amino glyoxals 1. Synthesis from α-amino acids and some condensation reactions with amines

Doi:10.1039/a907948c
(2000)

Article Doi