
Tetrahedron Letters p. 2375 - 2378 (1987)
Update date:2022-07-30
Topics:
Nagamatsu, Tomohisa
Kunieda, Takehisa
An effective procedure has been developed for the general synthesis of mixed alkyl or aryl phosphate esters by metal-catalyzed phosphorylation of alcohols with aryl bis(2-oxo-3-oxazolinyl)phosphinate.Among metallic acetylacetonates examined as catalysts, the zirconium complex was the most effective as in activity order of Zr(IV)> Ce(III)> Zn(II)> Mn(III)> Mn(II)-complexes.
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