Asymmetric Nitrogen. 72. Geminal Systems. 46. N-Chlorooxaaziridines: Optical Activation, Absolute Configuration, and Chiroptical Properties

DOI: 10.1021/ja00194a009

Source and publish data:

Journal of the American Chemical Society p. 4210 - 4215 (1989)

Update date:2022-08-03

Topics:

Authors:

Shustov, G.V.

Varlamov, S.V.

Chervin, I.I.

Aliev, A.E.

Kostyanovsky, R.G.

et al. et al.

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Article abstract of DOI:10.1021/ja00194a009

The chiroptical properties of N-chlorooxaziridines are reported as derived experimentally and by means of ab initio quantum mechanical calculations.The synthesis and optical resolution of 2-chloro-1-oxa-2-azaspiro<2.5>octane (1) and the diastereomeric 2-c

Full text of DOI:10.1021/ja00194a009

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