MICHAEL ADDITION OF NOVEL ACYL ANION EQUIVALENTS GENERATED BY THE ELECTROREDUCTION OF OXAZOLINIUM SALTS TO ACTIVATED OLEFINS

DOI: 10.1016/S0040-4039(00)96524-9

Source and publish data:

Tetrahedron Letters p. 4411 - 4414 (1987)

Update date:2022-08-04

Topics:

Authors:

Shono, Tatsuya

Kashimura, Shigenori

Yamaguchi, Yoshihide

Kuwata, Fumitaka

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Article abstract of DOI:10.1016/S0040-4039(00)96524-9

Electroreduction of oxazolinium salts gave novel acyl anion equivalents (AAEs), and the Michael addition of these AAEs to activated olefins has been found to be promoted effectively by the addition of chlorotrimethylsilane into the reaction system.This reaction was applied to the synthesis of cis-jasmone and dihydrojasmone.

Full text of DOI:10.1016/S0040-4039(00)96524-9

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