MICHAEL ADDITION OF NOVEL ACYL ANION EQUIVALENTS GENERATED BY THE ELECTROREDUCTION OF OXAZOLINIUM SALTS TO ACTIVATED OLEFINS

DOI: 10.1016/S0040-4039(00)96524-9

Source and publish data:

Tetrahedron Letters p. 4411 - 4414 (1987)

Update date:2022-08-04

Topics:

Authors:

Shono, Tatsuya

Kashimura, Shigenori

Yamaguchi, Yoshihide

Kuwata, Fumitaka

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96524-9

Electroreduction of oxazolinium salts gave novel acyl anion equivalents (AAEs), and the Michael addition of these AAEs to activated olefins has been found to be promoted effectively by the addition of chlorotrimethylsilane into the reaction system.This reaction was applied to the synthesis of cis-jasmone and dihydrojasmone.

Full text of DOI:10.1016/S0040-4039(00)96524-9

Products guided by the article

Product name:Cyclopentanone, 3-[3,4,4-trimethyl-2-(2-phenylethyl)-2-oxazolidinyl]-

Cas No:114066-03-4

R&D Labs maybe for 114066-03-4

Shenzhen Feiming Science and Technology Co,. Ltd

Contact:+86-755-85232577

Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.
Nanjing Fubang Chemical Co.,Ltd

Contact:+86-25-83179199

Address:5F,Tianzheng international plaza,No399 Zhongyang Road ,Nanjing China
Jewim Pharmaceutical (Shandong) Co., Ltd

Contact:+8615621883869

Address:山东省泰安市高新技术产业开发区配天门大街西首
ALPHA PHARMACEUTICAL CO，LTD JIANGSU

Contact:+86-527-84829968,+86-527-84829998

Address:suqian city
Jiande City Silibase Silicone New Material Manufacture Co., Ltd.

Contact:15967177856

Address:Genglou Industrial Development Area

Relevant to this article

Microwave-assisted rapid and efficient synthesis of C-alkyl imidazoisoquinolinone derivatives

Doi:10.1016/j.tetlet.2009.01.083
(2009)
On the synthesis of the first representatives of bis(benzo)-bispidinoaza- 14-crown-4 ethers

Doi:10.1007/s10593-008-0084-7
()
Features of the reaction of 2,3-dihalopropanoic acids with pyridines and nucleophilic addition to N-vinylpyridinium salts

Doi:10.1134/S107036320807030X
(2008)
A New Method for the Preparation of Conjugated Nitro Olefins

Doi:10.1246/cl.1992.933
(1992)
A copper-catalyzed, pH-neutral construction of high-enantiopurity peptidyl ketones from peptidic S-acylthiosalicylamides in air at room temperature

Doi:10.1002/anie.200804524
(2009)
Total synthesis of 11-deoxydaunomycinone by a new annulation process

Doi:10.1021/jo00248a014
(1988)

Article Doi