MICHAEL ADDITION OF NOVEL ACYL ANION EQUIVALENTS GENERATED BY THE ELECTROREDUCTION OF OXAZOLINIUM SALTS TO ACTIVATED OLEFINS

DOI: 10.1016/S0040-4039(00)96524-9

Source and publish data:

Tetrahedron Letters p. 4411 - 4414 (1987)

Update date:2022-08-04

Topics:

Authors:

Shono, Tatsuya

Kashimura, Shigenori

Yamaguchi, Yoshihide

Kuwata, Fumitaka

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96524-9

Electroreduction of oxazolinium salts gave novel acyl anion equivalents (AAEs), and the Michael addition of these AAEs to activated olefins has been found to be promoted effectively by the addition of chlorotrimethylsilane into the reaction system.This reaction was applied to the synthesis of cis-jasmone and dihydrojasmone.

Full text of DOI:10.1016/S0040-4039(00)96524-9

Products guided by the article

Product name:Cyclopentanone, 3-[3,4,4-trimethyl-2-(2-phenylethyl)-2-oxazolidinyl]-

Cas No:114066-03-4

R&D Labs maybe for 114066-03-4

Jiangsu Seed Chem Co.,Ltd.

Contact:86-513-84128750/13773795976

Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
WUXI KINGHAN BIO-MEDICAL&CHEMICAL INC.

Contact:13861062998

Address:Room 1316,No.1619 Huishan Avenue,Wuxi,China
Hangzhou Deli Chemical Co.,Ltd.

website:http://www.dlchemical.com

Contact:86 571 28006267

Address:Tangxi Industrial Area, Yuhang District, Hangzhou
Tianjin Boron PharmaTech Co.,Ltd.(expird)

Contact:86-022-59845187

Address:B9-401, Tianda Science Park,No.80,4th Avenue,TEDA,Tianjin, China
Hebei DaPeng Pharm & Chem Co., Ltd.

Contact:86-317-7298678,0576-88861898 88861908

Address:West Songmen Village, East Songmen Town, Wuqiao, Cangzhou, Hebei ,China

Relevant to this article

Microwave-assisted rapid and efficient synthesis of C-alkyl imidazoisoquinolinone derivatives

Doi:10.1016/j.tetlet.2009.01.083
(2009)
On the synthesis of the first representatives of bis(benzo)-bispidinoaza- 14-crown-4 ethers

Doi:10.1007/s10593-008-0084-7
()
Features of the reaction of 2,3-dihalopropanoic acids with pyridines and nucleophilic addition to N-vinylpyridinium salts

Doi:10.1134/S107036320807030X
(2008)
A New Method for the Preparation of Conjugated Nitro Olefins

Doi:10.1246/cl.1992.933
(1992)
A copper-catalyzed, pH-neutral construction of high-enantiopurity peptidyl ketones from peptidic S-acylthiosalicylamides in air at room temperature

Doi:10.1002/anie.200804524
(2009)
Total synthesis of 11-deoxydaunomycinone by a new annulation process

Doi:10.1021/jo00248a014
(1988)

Article Doi