Asymmetric 1,3-Dipolar Cycloadditions of Nitrile Oxides Using Simple Chiral Auxiliaries

DOI: 10.1021/jo00246a014

Source and publish data:

Journal of Organic Chemistry p. 2468 - 2472 (1988)

Update date:2022-09-26

Topics:

Authors:

Olsson, Thomas

Stern, Kaye

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00246a014

Dipolar cycloadditions of nitrile oxides to substituted bornyl crotonates give substituted isoxazolines with up to 80percent diastereoselectivity.Both regioisomers of the adducts are produced in a ratio of approximately 3:1, independent of the substituent

Full text of DOI:10.1021/jo00246a014

Products guided by the article

Product name:(4R,5R)-4-Methyl-3-phenyl-4,5-dihydro-isoxazole-5-carboxylic acid (1R,2S,4R)-1,7,7-trimethyl-2-phenyl-bicyclo[2.2.1]hept-2-yl ester

Cas No:114156-65-9

R&D Labs maybe for 114156-65-9

Wuhan Jadechem International Trade Co.,Ltd.

website:http://www.jadechem-intl.com

Contact:+86-27-83527060

Address:Room 502,Building C11,Software new city No.8,Huacheng Avenue,East Lake High-tech development zone,Wuhan,Hubei,China
Watson International Ltd

Contact:+44 (0)2036089360-31

Address:Chanceryhouse,Chancery Lan
LinHai Cina Chemical Co., LTD.

Contact:0576-85580989

Address:Pharma-chem zone,Duqiao,Linhai,Zhejiang,China
Jiangsu Mingchem Corporation

website:http://www.mingchem.com/en/index

Contact:0519-85170101-802

Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China

Relevant to this article

Total synthesis of specionin - natural product or artifact ?

Doi:10.1016/S0040-4039(00)96648-6
(1987)
Conjugated polymers containing electron-deficient main chains and electron-rich pendant groups: Synthesis and application to electroluminescence

Doi:10.1016/j.orgel.2011.03.020
(2011)
Scavenge-ROMP-filter: a facile strategy for soluble scavenging via norbornenyl tagging of electrophilic Reagents.

Doi:10.1021/ol0257880
(2002)
On the early steps of cineol biosynthesis in Eucalyptus globulus

Doi:10.1002/1522-2675(20000906)83:9<2504::AID-HLCA2504>3.0.CO;2-Z
(2000)
The Total Synthesis of (-)-Litsenolides C-1 and C-2

Doi:10.1039/P19870002681
(1987)
The new metabolite (S)-cinnamoylphosphoramide from Streptomyces sp. and its total synthesis

Doi:10.1002/ejoc.200800654
(2008)

Article Doi