Journal of the Chemical Society. Chemical communications p. 1007 - 1008 (1987)
Update date:2022-08-03
Topics:
Blattner, Regine
Ferrier, Robert J.
Renner, Robyn
Free redicals produced successively at C-5 and C-1 from corresponding D-xylopyranose-based bromides add to acrylonitrile and methyl acrylate to give products with β-propionitrile or β-propionate substituents at these positions; some steric control can be achieved in the reactions, and the 4,8-anhydroundecanose derivative (13) is produced with good selectivity.
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