Carbohydrate Research p. 297 - 312 (1987)
Update date:2022-08-05
Topics:
Fuegedi, Peter
Birberg, Winnie
Garegg, Per J.
Pilotti, Ake
Synteses are described of a D-glucose heptasaccharide, 1, corresponding to a glucan structure recognised by the soybean when infected by the fungus Phytophtora megasperma f. sp. glycinea and which stimulates the formation of phytoalexins.The synthetic strategy is based upon 1,2-trans-glycoside formation assisted by participating benzoate groups in the 2-position, with silver triflate as promoter and glycosyl bromides as donors for making the smaller fragments, and with methyl triflate as promoter with thioglycosides as donors for making the larger ones.Regioselective reductive openings of 4,6 benzylidene acetals play a key role in obtaining free 6-OH groups with benzyl protection at O-4.
View MoreShanghai Balmxy Pharmaceutical Co., Ltd
Contact:0086-21-24206007
Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China
Changzhou Hopschain Chemical Co.,Ltd
website:http://www.hopschem.cn/products.html
Contact:86-519-85528066
Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China
KAIYUAN CHEMICAL COMPANY LIMITED.
website:http://www.kaiyuanchem.com
Contact:+86-22-59891255/66/77
Address:B-2205, Kuangshi International Building, Yingbin Road, XiangLuo Bay Business District, Binhai New area, Tianjin, China.
Contact:+86-518-81061113
Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
Daicel Chiral Technologies (China)CO.,LTD
Contact:021-5046-0086*8
Address:Part C, FL 5, the 16th Building, No. 69, XiYa Road, WaiGaoQiao Free Trade Zone, Shanghai, 200131, P.R.China
Doi:10.1021/ic802407x
(2009)Doi:10.1016/j.bmcl.2009.01.042
(2009)Doi:10.1016/j.bmcl.2009.12.086
(2010)Doi:10.1016/j.phytochem.2008.12.012
(2009)Doi:10.1016/S0020-1693(00)80240-6
(1991)Doi:10.1021/jm201708h
(2012)