Asymmetric Synthesis Using Chiral Piperazine. I. Asymmetric Synthesis of 2-Substituted Alcohol and Carboxylic Acid by Diastereoselective Alkylation of Chiral Diamides Derived from Piperazines

DOI: 10.1246/bcsj.60.3450

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3450 - 3452 (1987)

Update date:2022-08-04

Topics:

Authors:

Soai, Kenso

Hayashi, Hiroshi

Shinozaki, Akihiro

Umebayashi, Hideaki

Yamada, Yasuyuki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.60.3450

The diastereoselective alkylation of chiral diamides derived from chiral piperazines afforded optically active alcohols and acids in moderate enantiomeric excesses (up to 68percent e.e.).

Full text of DOI:10.1246/bcsj.60.3450

Products guided by the article

Product name:Piperazine, 2,5-bis(1-methylethyl)-, trans- (9CI)

Cas No:114420-45-0

R&D Labs maybe for 114420-45-0

Wuxi Morality Chemical Co., Ltd(expird)

Contact:

Address:B/7F, 321th WuYun Rd, Wanda Plaza, Wuxi City, 214174, China
Zhengzhou Xinlian Chemical Tech Co. ,Ltd

Contact:0371-65771781 021-52042910

Address:H Part, Building I, No. 700 Gonglu Road, Pudong New Area, Shanghai
LINAN HAIHUA CHEMICAL CO LTD

Contact:86-571-61063068

Address:LINAN
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.

Contact:86-716-8331612

Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
Wuxi D-Stone International Co., Ltd.

Contact:+86-510-82740567

Address:21F Hengtong Int'l Centre, 215Zhongshan Road, Wuxi, Jiangsu,China

Relevant to this article

Investigation of the polarographic properties and potential carcinogenity of some hydroxyurea derivatives by DC polarography

Doi:10.1135/cccc19960656
(1996)
Four novel coordination frameworks with high degree of diamondoid interpenetration containing scarce quadruple-stranded homo-axis helices and quintuple-stranded molecular braids

Doi:10.1016/j.ica.2016.04.018
(2016)
A convenient approach to polycyclic derivatives with a cis-fused 2,6-dioxabicyclo[4.3.0]nonane system by the sequence ring-opening/intramolecular Ring-closing enyne metathesis/diels-alder reaction

Doi:10.1002/ejoc.200800936
(2009)
Iron-catalysed fluoroaromatic coupling reactions under catalytic modulation with 1,2-bis(diphenylphosphino)benzene

Doi:10.1039/b820879d
(2009)
Engineering self-assembled fluorescent organic nanotapes and submicrotubes from π-conjugated molecules

Doi:10.1039/b925459e
(2010)
STEREOSPECIFIC SYNTHESIS OF 2-THIOPHOSPHATIDYLCHOLINES; A NEW CLASS OF BIOLOGICALLY ACTIVE PHOSPHOLIPID ANALOGUES

Doi:10.1016/S0040-4039(00)96379-2
(1987)

Article Doi