Asymmetric Synthesis Using Chiral Piperazine. I. Asymmetric Synthesis of 2-Substituted Alcohol and Carboxylic Acid by Diastereoselective Alkylation of Chiral Diamides Derived from Piperazines

DOI: 10.1246/bcsj.60.3450

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3450 - 3452 (1987)

Update date:2022-08-04

Topics:

Authors:

Soai, Kenso

Hayashi, Hiroshi

Shinozaki, Akihiro

Umebayashi, Hideaki

Yamada, Yasuyuki

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Article abstract of DOI:10.1246/bcsj.60.3450

The diastereoselective alkylation of chiral diamides derived from chiral piperazines afforded optically active alcohols and acids in moderate enantiomeric excesses (up to 68percent e.e.).

Full text of DOI:10.1246/bcsj.60.3450

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