Asymmetric Synthesis Using Chiral Piperazine. I. Asymmetric Synthesis of 2-Substituted Alcohol and Carboxylic Acid by Diastereoselective Alkylation of Chiral Diamides Derived from Piperazines

DOI: 10.1246/bcsj.60.3450

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3450 - 3452 (1987)

Update date:2022-08-04

Topics:

Authors:

Soai, Kenso

Hayashi, Hiroshi

Shinozaki, Akihiro

Umebayashi, Hideaki

Yamada, Yasuyuki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.60.3450

The diastereoselective alkylation of chiral diamides derived from chiral piperazines afforded optically active alcohols and acids in moderate enantiomeric excesses (up to 68percent e.e.).

Full text of DOI:10.1246/bcsj.60.3450

Products guided by the article

Product name:Piperazine, 2,5-bis(1-methylethyl)-, trans- (9CI)

Cas No:114420-45-0

R&D Labs maybe for 114420-45-0

Xi'an Kaixiang Photoelectric Technology Co., Ltd

website:http://www.kxmaterials.com/

Contact:86-29-15991651477

Address:Building 6, Biopharmaceutical Industry R&D Cluster Base, No. 16, Caotang 4th Road, Caotang Science and Technology Industrial Base, High-tech Zone, Xi'an City, Shaanxi Province, China
Tianjin Jingye Fine Chemicals Co., Ltd.

Contact:+86-15722078107; +86-22-26911407

Address:Bohua Fine Chemicals Base of Petrochemical Industry Park, Nanhuan Road, Dagang District, Tianjin, 300271, P. R. China
Changsha Yonta Industry Co., Ltd.

Contact:+ 86-731-8535 2228

Address:Rm.1717, North Bldg., No.368, East 2nd Ring Road(2nd Section)
Shandong Dayi Chemical Co., Ltd.

website:http://www.dayi.com.cn

Contact:+86- 535-7388728. 15306386031

Address:No 1 Danya west road, Laiyang City, Shandong province
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China

Relevant to this article

Investigation of the polarographic properties and potential carcinogenity of some hydroxyurea derivatives by DC polarography

Doi:10.1135/cccc19960656
(1996)
Four novel coordination frameworks with high degree of diamondoid interpenetration containing scarce quadruple-stranded homo-axis helices and quintuple-stranded molecular braids

Doi:10.1016/j.ica.2016.04.018
(2016)
A convenient approach to polycyclic derivatives with a cis-fused 2,6-dioxabicyclo[4.3.0]nonane system by the sequence ring-opening/intramolecular Ring-closing enyne metathesis/diels-alder reaction

Doi:10.1002/ejoc.200800936
(2009)
Iron-catalysed fluoroaromatic coupling reactions under catalytic modulation with 1,2-bis(diphenylphosphino)benzene

Doi:10.1039/b820879d
(2009)
Engineering self-assembled fluorescent organic nanotapes and submicrotubes from π-conjugated molecules

Doi:10.1039/b925459e
(2010)
STEREOSPECIFIC SYNTHESIS OF 2-THIOPHOSPHATIDYLCHOLINES; A NEW CLASS OF BIOLOGICALLY ACTIVE PHOSPHOLIPID ANALOGUES

Doi:10.1016/S0040-4039(00)96379-2
(1987)

Article Doi