Journal of Organometallic Chemistry p. 85 - 91 (1991)
Update date:2022-07-29
Topics:
Nasim, Mohammed
Livantsova, L. I.
Zaitseva, G. S.
Lorberth, J.
Interaction of the readily available 1-trimethylsiloxygermatranes (1a, 1b) with various halogenating reagents (Me3SiBr, Me3SiI, HF and SOCl2) has given the 1-halogermatranes (2a-2f).The 1-halogermatranes (2a, 2b) have been converted into the corresponding 1-organoxygermatranes by treatment with trialkylalkoxystannanes (3a-3f).The corresponding 1-organoxygermatranes (4d, 4e, 4f) were made by interaction of 1-hydroxygermatrane monohydrate with the corresponding hydroxy derivatives).
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