
Journal of Organometallic Chemistry p. 275 - 280 (1987)
Update date:2022-08-04
Topics:
Smith, Graham
O'Reilly, Eric J.
Reynolds, Bradley J.
Kennard, Colin H. L.
Mak, Thomas C. W.
The crystal structure of silver(I) 2,4,5-trichlorophenolate has been determined by X-ray diffraction and refined to a residual R = 0.031 for 1072 observed reflections.Crystals are orthorhombic, space group Pccn with 8 molecules in a cell of dimensions, a 11.455(4), b 23.75(1), c 5.645(1) Angstroem.Each silver in the polymeric structure is bonded to three independent phenolate oxygens (Ag-O range, 2.317-2.543(3) Angstroem; O-Ag-O range, 86.5-106.5(2) deg).In addition there is an unusual symmetrical and directed carbon-silver bond (Ag-C, 2.443(5) Angstroem) that completes a trigonal pyramidal stereochemistry about silver.
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