Palladium-Catalyzed Reaction of Propargylic Acetates with Carbonyl Compounds by SmI2

DOI: 10.1246/cl.1987.2275

Source and publish data:

Chemistry Letters p. 2275 - 2278 (1987)

Update date:2022-08-03

Topics:

Authors:

Tabuchi, Takanori

Inanaga, Junji

Yamaguchi, Masaru

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Article abstract of DOI:10.1246/cl.1987.2275

Reductive addition of propargylic acetates to carbonyl compounds proceeded smoothly at room temperature by using SmI2 and a catalytic amount of Pd(PPh3)4 to give the corresponding acetylenic and/or allenic alcohols with appreciable seletivity.The method i

Full text of DOI:10.1246/cl.1987.2275

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