AN ENANTIODIFFERENTIATING CONVERSION OF RACEMIC 1,3-ALKANEDIOLS INTO ENANTIOMERICALLY PURE MATERIALS

DOI: 10.1016/S0040-4039(00)96641-3

Source and publish data:

Tetrahedron Letters p. 4847 - 4848 (1987)

Update date:2022-08-04

Topics:

Authors:

Harada, Toshiro

Kurokawa, Hideaki

Oku, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96641-3

Titanium tetrachloride promoted ring-cleavage reaction of a mixture of diastereomeric spiroketals derived from racemic 1,3-alkanediols and l-menthone, followed by benzoylation by Mitsunobu reaction, and the subsequent hydrolysis gave enantiomerically pure 1,3-alkanediols.

Full text of DOI:10.1016/S0040-4039(00)96641-3

Products guided by the article

Product name:2-[(1R,2S,5R)-1-((S)-3-Hydroxy-5-phenyl-pentyloxy)-2-isopropyl-5-methyl-cyclohexyl]-1-phenyl-ethanone

Cas No:115346-77-5

R&D Labs maybe for 115346-77-5

Jiangsu Jiuri Chemical Co.,Ltd.

Contact:+86-519-82118868

Address:Tianwang Town, Jurong City, Jiangsu Province, China
Shenzhen HwaGen Pharmaceutical Co., Ltd

website:http://www.rafflespt.com

Contact:+86-752-5538396

Address:Guangdong Huizhou China
Suzhou Ryan Pharmachem Technology Co.,Ltd

Contact:+86-0512-68780025

Address:B-301,No.2 Taishan Road,Suzhou New District,Jiangsu,P.R. China
Shanghai Yuantai Chemical Products Co., Ltd

Contact:021--66129803

Address:Chengyin Road,Shanghai,China
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.

Relevant to this article

Selective, catalytic aerobic oxidation of alcohols using CuBr₂ and bifunctional triazine-based ligands containing both a bipyridine and a TEMPO group

Doi:10.1039/b820554j
(2009)
Cobalt carbonyl complexes with bridging diphosphine ligands

Doi:10.1021/om00031a052
(1993)
Palladium-Catalyzed Direct β-C?H Arylation of Ketones with Arylboronic Acids in Water

Doi:10.1002/adsc.201700277
(2017)
Rapid and convenient thioester synthesis under phase-transfer catalysis conditions

Doi:10.1080/10426501003713072
(2010)
Characterization of B-5354c, a new sphingosine kinase inhibitor, produced by a marine bacterium

Doi:10.7164/antibiotics.53.759
(2000)
Complementary diastereoselectivity in the intermolecular addition of titanium and magnesium naphtholates to asymmetric lactaldehydes

Doi:10.1039/a901456j
(1999)

Article Doi