AN ENANTIODIFFERENTIATING CONVERSION OF RACEMIC 1,3-ALKANEDIOLS INTO ENANTIOMERICALLY PURE MATERIALS

DOI: 10.1016/S0040-4039(00)96641-3

Source and publish data:

Tetrahedron Letters p. 4847 - 4848 (1987)

Update date:2022-08-04

Topics:

Authors:

Harada, Toshiro

Kurokawa, Hideaki

Oku, Akira

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Article abstract of DOI:10.1016/S0040-4039(00)96641-3

Titanium tetrachloride promoted ring-cleavage reaction of a mixture of diastereomeric spiroketals derived from racemic 1,3-alkanediols and l-menthone, followed by benzoylation by Mitsunobu reaction, and the subsequent hydrolysis gave enantiomerically pure 1,3-alkanediols.

Full text of DOI:10.1016/S0040-4039(00)96641-3

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