RESOLUTION OF 1,3-ALKANEDIOLS VIA CHIRAL SPIROKETALS DERIVED FROM l-MENTHONE

DOI: 10.1016/S0040-4039(00)96640-1

Source and publish data:

Tetrahedron Letters p. 4843 - 4846 (1987)

Update date:2022-07-29

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Authors:

Harada, Toshiro

Kurokawa, Hideaki

Oku, Akira

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Article abstract of DOI:10.1016/S0040-4039(00)96640-1

Ketalization reaction of racemic 1,3-alkanediols with l-menthone gave a mixture of diastereomeric spiroketals that was easily separated by silica gel column chromatography and converted into enantiomerically pure diols by acid-catalyzed hydrolysis.

Full text of DOI:10.1016/S0040-4039(00)96640-1

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