Acetal-bond Cleavage of 4,6-Alkylidenehexopyranosides by Diisobutylaluminium Hydride and by Lithium Triethylborohydride-TiCl4

DOI: 10.1246/cl.1987.2033

Source and publish data:

Chemistry Letters p. 2033 - 2036 (1987)

Update date:2022-09-26

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Authors:

Mikami, Tetsuhiro

Asano, Hiroyuki

Mitsunobu, Oyo

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Article abstract of DOI:10.1246/cl.1987.2033

Regioselective acetal-bond cleavage of 4,6-benzylidene- and 4,6-O-(4-methoxybenzylidene)-α-D-altropyranosides by DIBAL or Li(C2H5)3BH-TiCl4 is described.The sense of regioselectivity could be controlled by suitable choice of the protecying group of hydrox

Full text of DOI:10.1246/cl.1987.2033

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