Acetal-bond Cleavage of 4,6-Alkylidenehexopyranosides by Diisobutylaluminium Hydride and by Lithium Triethylborohydride-TiCl4

DOI: 10.1246/cl.1987.2033

Source and publish data:

Chemistry Letters p. 2033 - 2036 (1987)

Update date:2022-09-26

Topics:

Authors:

Mikami, Tetsuhiro

Asano, Hiroyuki

Mitsunobu, Oyo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1987.2033

Regioselective acetal-bond cleavage of 4,6-benzylidene- and 4,6-O-(4-methoxybenzylidene)-α-D-altropyranosides by DIBAL or Li(C2H5)3BH-TiCl4 is described.The sense of regioselectivity could be controlled by suitable choice of the protecying group of hydrox

Full text of DOI:10.1246/cl.1987.2033

Products guided by the article

Product name:(2R,3S,4S,5S,6S)-4-Benzyloxy-2-benzyloxymethyl-6-methoxy-5-(2-methyl-allyl)-tetrahydro-pyran-3-ol

Cas No:115414-38-5

R&D Labs maybe for 115414-38-5

nanjing suru chemical co.ltd

Contact:+86-025-52406782

Address:8 Taizishan Rd., Yanjiang Industrial Development Area, Nanjing, Jiangsu, China.
Phantom-pharma

Contact:

Address:
Weifang Dongxing Chitosan Factory

website:http://dxchitosan.lookchem.com/

Contact:13475651157

Address:Weifang city ,shandong province
LIDE PHARMACEUTICALS LIMITED

website:http://www.lidepharma.com

Contact:+86-25-58409506

Address:Chungking Express Nos.36 Nathan Road，Kowloon, HK
Taizhou Elitechemie MediPharma Technology Co.,Ltd.

Contact:+86-523-86810021

Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China

Relevant to this article

Design of novel inhibitors of aminopeptidases. Synthesis of peptide-derived diamino thiols and sulfur replacement analogues of bestatin

Doi:10.1021/jm00119a023
(1988)
SYNTHESIS, THREE-DIMENSIONAL STRUCTURE, AND STEREOCHEMISTRY OF EPOXIDATION OF 1-CHLORO-2-METHYLENECYCLOHEXANE

Doi:10.1007/BF00962664
(1988)
Trifluoromethylfluorosulfonylation of Unactivated Alkenes Using Readily Available Ag(O₂CCF₂SO₂F) and N-Fluorobenzenesulfonimide

Doi:10.1002/anie.201709663
(2017)
The first ligand-modulated oxidative Heck vinylation. Efficient catalysis with molecular oxygen as palladium(0) oxidant

Doi:10.1039/b311492a
(2004)
Synthesis and bioactivity of a side chain bridged paclitaxel: A test of the T-Taxol conformation

Doi:10.1016/j.bmcl.2009.03.063
(2009)
INCORPORATION OF MOLECULAR NITROGEN INTO AMIDES AND IMIDES BY USE OF TITANIUM-NITROGEN COMPLEXES

Doi:10.1016/S0040-4039(00)61842-7
(1987)

Article Doi