Journal of the Chemical Society. Perkin transactions II p. 865 - 868 (1988)
Update date:2022-09-26
Topics:
Arjona, Odon
Mallo, Araceli
Manzano, Cristina
Plumet, Joaquin
Galbis, Juan
Jaime, Carlos
The stereochemistry of formation of Schiff's bases derived from norbornen-2-one and 7-oxanorbornen-2-one has been studied by (1)H and (13)C n.m.r. spectroscopy.Elucidation of the reason for the preference for the E-isomer in both cases has been attempted by molecular mechanics calculations.This preference may be justified by A1,3 allylic interactions.
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