Role of the A1,3 Allylic Interaction on the Stereochemistry of Formation of Schiff's Bases derived from Bicyclohept-5-en-2-one and 7-Oxabicyclohept-5-en-2-one

DOI: 10.1039/P29880000865

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 865 - 868 (1988)

Update date:2022-09-26

Topics:

Authors:

Arjona, Odon

Mallo, Araceli

Manzano, Cristina

Plumet, Joaquin

Galbis, Juan

Jaime, Carlos

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P29880000865

The stereochemistry of formation of Schiff's bases derived from norbornen-2-one and 7-oxanorbornen-2-one has been studied by (1)H and (13)C n.m.r. spectroscopy.Elucidation of the reason for the preference for the E-isomer in both cases has been attempted by molecular mechanics calculations.This preference may be justified by A^1,3 allylic interactions.

Full text of DOI:10.1039/P29880000865

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:N-benzyl-7-oxabyclo<2.2.1>hept-5-en-2-ylimine

Cas No:115880-15-4

R&D Labs maybe for 115880-15-4

New Forms

Contact:+31-24-3886056

Address:Binderskampweg 29 Unit 36
Chongqing Rong＆Quan Pharmaceutical Technology Co. , Ltd.

Contact:86-023-65268721

Address:No. 7, Manshanhong Village, Pingdingshan, Shapingba District, Chongqing Province, China
Buffett (China) Holding Co.,Ltd

Contact:4006570891

Address:
Shandong Hongxiang Zinc Co., Ltd

Contact:086-0311-66187879

Address:DaWang developing zone
Nanjing distinctions Medical Technology Co., Ltd.(expird)

Contact:+86-15996203785 13914714059

Address:nanjing,jiangsu , China

Relevant to this article

Addressing the Structural Complexity of Fluorinated Glucose Analogues: Insight into Lipophilicities and Solvation Effects

Doi:10.1002/chem.202002825
(2020)
(Phosphine)carbonylnitrosylacylcobaltate Complexes as Acyl Transfer Reagents. Acylation of Allylic Halides, Conjugated Enones, and Quinones

Doi:10.1021/jo00224a061
(1985)
Synthesis and Characterisation of a Triple Cluster of Gold and Boron

Doi:10.1039/c39850000819
(1985)
REDUKTIVE METHYLIERUNG PRIMAERER UND SEKUNDAERER AMINE MIT HILFE VON FORMALDEHYD UND SALZEN DER PHOSPHORIGEN SAEURE

Doi:10.1016/S0040-4039(01)81224-7
(1984)
Domino reaction of a gold catalyzed 5-: Endo-dig cyclization and a [3,3]-sigmatropic rearrangement towards polysubstituted pyrazoles

Doi:10.1039/c8ob02807a
(2018)
Heterocyclization of 1-aryl/alkyl-2-thiobiureas to 4-aryl/alkyl-3-substituted-Δ²-1,2,4-triazolin-5-ones

Doi:10.1016/S0040-4020(01)00018-7
(2001)

Article Doi