Regioselective and Stereoselective Oxirane Ring-Openings of 2,3-Anhydropentopyranosides with Some Methyl Group Donating Organometallic Reagents

DOI: 10.1021/jo00254a023

Source and publish data:

Journal of Organic Chemistry p. 4542 - 4548 (1988)

Update date:2022-07-29

Topics:

Authors:

Inghardt, Tord

Frejd, Torbjoern

Magnusson, Goeran

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00254a023

By the proper choice of methyl group transferring reagents organometallic (Me4AlLi, Me4AlLi/MeLi (1:1), Me2CuLi, Me3Al, Me2Mg) it is possible to selectively introduce a methyl group into the 2- or 3-position via epoxide ring-opening of four easily availab

Full text of DOI:10.1021/jo00254a023

Products guided by the article

Product name:benzyl 2,3-anhydro-4-O-(tert-butyldimethylsilyl)-β-L-ribopyranoside

Cas No:115983-56-7

R&D Labs maybe for 115983-56-7

Tianjin SPHINX SCIENTIFIC LAB.

Contact:+86-022-66211289

Address:Tianda high-tech Park. No.80,the 4th Avenue
Hebei Think-Do Environment Co., Ltd

website:http://www.thinkdo-environment.com

Contact:0311-86510809

Address:No 6, Shilian Middle Street, Circular Chemical Industry Park
New Forms

Contact:+31-24-3886056

Address:Binderskampweg 29 Unit 36
Chemtrade International ( China )

Contact:+86-532-86893005

Address:Rm 2-501, Huaxia Zonghe Building, No. 410 JInggangshan Road, Huangdao
Tianjin Jiuri New Materials Co., Ltd.

Contact:+86-22-58889220

Address:C-5/6, Vison Hill, No.1 Gonghua Road, Huayuan Hi-tech Park, Tianjin, China.

Relevant to this article

Asymmetric transfer hydrogenation of aromatic ketones in water using a polymer-supported chiral catalyst containing a hydrophilic pendant group

Doi:10.1002/adsc.200800362
(2008)
Stereoselective synthesis of (1′S,3R,4R)-4-acetoxy-3-(2′-fluoro-1′-trimethylsilyloxyethyl)-2-azetidinone

Doi:10.1016/j.tetlet.2009.03.111
(2009)
A new method for regioselective introduction of trifluoromethyl groups into heteroarenes; Part 1. Synthesis of trifluoromethyl-substituted 1,3-azoles (oxazoles, thiazoles, imidazoles)

Doi:10.1055/s-1988-27509
(1988)
Self-assembled hexadecanitroxide

Doi:10.1021/ol901028h
(2009)
Novel 5-(3-(substituted)-4,5-dihydroisoxazol-5-yl)-2-methoxyphenyl derivatives: Synthesis and anticancer activity

Doi:10.1071/CH07395
(2008)
Optimization of a novel class of benzimidazole-based farnesoid X receptor (FXR) agonists to improve physicochemical and ADME properties

Doi:10.1016/j.bmcl.2010.12.123
(2011)

Article Doi