Regioselective and Stereoselective Oxirane Ring-Openings of 2,3-Anhydropentopyranosides with Some Methyl Group Donating Organometallic Reagents

DOI: 10.1021/jo00254a023

Source and publish data:

Journal of Organic Chemistry p. 4542 - 4548 (1988)

Update date:2022-07-29

Topics:

Authors:

Inghardt, Tord

Frejd, Torbjoern

Magnusson, Goeran

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Article abstract of DOI:10.1021/jo00254a023

By the proper choice of methyl group transferring reagents organometallic (Me4AlLi, Me4AlLi/MeLi (1:1), Me2CuLi, Me3Al, Me2Mg) it is possible to selectively introduce a methyl group into the 2- or 3-position via epoxide ring-opening of four easily availab

Full text of DOI:10.1021/jo00254a023

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