Regioselective and Stereoselective Oxirane Ring-Openings of 2,3-Anhydropentopyranosides with Some Methyl Group Donating Organometallic Reagents

DOI: 10.1021/jo00254a023

Source and publish data:

Journal of Organic Chemistry p. 4542 - 4548 (1988)

Update date:2022-07-29

Topics:

Authors:

Inghardt, Tord

Frejd, Torbjoern

Magnusson, Goeran

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00254a023

By the proper choice of methyl group transferring reagents organometallic (Me4AlLi, Me4AlLi/MeLi (1:1), Me2CuLi, Me3Al, Me2Mg) it is possible to selectively introduce a methyl group into the 2- or 3-position via epoxide ring-opening of four easily availab

Full text of DOI:10.1021/jo00254a023

Products guided by the article

Product name:benzyl 2,3-anhydro-4-O-(tert-butyldimethylsilyl)-β-L-ribopyranoside

Cas No:115983-56-7

R&D Labs maybe for 115983-56-7

Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Qingdao biskanten bio-tech Co,.Ltd

Contact:86-532-86996732/87122377

Address:Shandong Province Qingdao Changjiang Road No.366
Jiangsu Cale New Material Co.ltd

Contact:+86-515-88334667/88203550

Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
Anhui Eapearl Chemical Co., Ltd.

Contact:86-562-5858458

Address:358 South Huaihe Road
Changyi Xinxing Technology Development Co., Ltd.

Contact:0086-510-86651065(Time Zone:8),86651656

Address:94 Yingbinxilu WestRoad, Huangtu Town, Jiangyin City, Jiangsu, China

Relevant to this article

Asymmetric transfer hydrogenation of aromatic ketones in water using a polymer-supported chiral catalyst containing a hydrophilic pendant group

Doi:10.1002/adsc.200800362
(2008)
Stereoselective synthesis of (1′S,3R,4R)-4-acetoxy-3-(2′-fluoro-1′-trimethylsilyloxyethyl)-2-azetidinone

Doi:10.1016/j.tetlet.2009.03.111
(2009)
A new method for regioselective introduction of trifluoromethyl groups into heteroarenes; Part 1. Synthesis of trifluoromethyl-substituted 1,3-azoles (oxazoles, thiazoles, imidazoles)

Doi:10.1055/s-1988-27509
(1988)
Self-assembled hexadecanitroxide

Doi:10.1021/ol901028h
(2009)
Novel 5-(3-(substituted)-4,5-dihydroisoxazol-5-yl)-2-methoxyphenyl derivatives: Synthesis and anticancer activity

Doi:10.1071/CH07395
(2008)
Optimization of a novel class of benzimidazole-based farnesoid X receptor (FXR) agonists to improve physicochemical and ADME properties

Doi:10.1016/j.bmcl.2010.12.123
(2011)

Article Doi