Journal of Organic Chemistry p. 4730 - 4735 (1988)
Update date:2022-08-05
Topics: Synthesis Chiral Catalyst Stereoselective High-performance liquid chromatography (HPLC) Diastereomers Reaction Substrate erythronolide A
Hoagland, Steven
Morita, Yasushi
Bai, Dong Lu
Maerki, Hans-Peter
Kees, Kenneth
et al.
Enantiomerically pure ketone 2, corresponding to the C-8, C-15 segment of erythronolide A, has been prepared by a 12-step route with crotyl alcohol as starting material in 5-6percentoveral yield.The synthesis starts with trisylhydrazone 4, which is conver
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