TRANSMETALLATION OF N-(TRIALKYLSTANNYL)METHYLIMINES. A NEW METHOD FOR THE GENERATION AND CYCLOADDITION OF 2-AZAALLYL ANIONS.

DOI: 10.1016/S0040-4039(00)80203-8

Source and publish data:

Tetrahedron Letters p. 761 - 764 (1988)

Update date:2022-08-02

Topics:

Authors:

Pearson, William H.

Szura, Daniel P.

Harter, William G.

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Article abstract of DOI:10.1016/S0040-4039(00)80203-8

Transmetallation of imines 1 at -78 deg C with RLi provided 2-azaallyl anions 2, which readily undergo cycloaddition with olefinic anionophiles, providing pyrrolidines.Of particular note is the generation of unstabilized 2-azaallyl anions for the first ti

Full text of DOI:10.1016/S0040-4039(00)80203-8

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