Enantioselective Photoreactions of Cycloocta-2,4,6-trien-1-one and Cycloocta-2,4-dien-1-one in Their Inclusion Complexes with (R,R)-(-)-1,6-Bis(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol: Mechanistic Study Based on X-ray Crystal Structure Analyse

DOI: 10.1021/jo00302a014

Source and publish data:

Journal of Organic Chemistry p. 4532 - 4537 (1990)

Update date:2022-08-02

Topics:

Authors:

Fujiwara, Takaji

Nanba, Nobutsugu

Hamada, Kensaku

Toda, Fumio

Tanaka, Koichi

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Article abstract of DOI:10.1021/jo00302a014

A host molecule, (R,R)-(-)-1,6-bis(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol (1), includes two enantiomers (2a and 2b) of a guest molecule, cycloocta-2,4,6-trien-1-one (2), and gives the crystalline complex I (host:guest = 1:2).On the other hand

Full text of DOI:10.1021/jo00302a014

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