Chemistry Letters p. 2029 - 2032 (1987)
Update date:2022-07-29
Topics:
Wakamatsu, Kuni
Oshima, Koichiro
Utimoto, Kiitiro
Treatment of 1-propenyltriphenylsilane with n-BuLi in THF-HMPA provides (triphenylsilyl)allyl anion which is identical with an anion derived from 2-propenyltriphenylsilane and base.Generation of (triphenylgermyl)allyl anion is also described.Addition of alkyl halides or carbonyl compounds to these anions gives the corresponding adducts regioselectively.
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Doi:10.1021/jo00255a052
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(2015)Doi:10.1021/acscatal.6b01421
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(1987)
