A NOVEL CONSTRUCTION OF OCTAHYDRO-3a,7-ETHANO-3aH-INDENE SKELETON FROM A TRICYCLO2,8>OCTANE: A TOTAL SYNTHESIS OF (+/-)-DESCARBOXYQUADRONE

DOI: 10.1016/S0040-4039(00)84743-7

Source and publish data:

Tetrahedron Letters p. 3161 - 3164 (1986)

Update date:2022-07-29

Topics:

Authors:

Imanishi, Takeshi

Matsui, Munetaka

Yamashita, Masayuki

Iwata, Chuzo

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Article abstract of DOI:10.1016/S0040-4039(00)84743-7

Total synthesis of (+/-)-descarboxyquadrone was achieved via a regioselective C1-C2 bond cleavage of 7,7-dimethyl-5-(2-propenyl)-tricyclo(3.3.0.0^2,8)octan-3-one as a crucial step.

Full text of DOI:10.1016/S0040-4039(00)84743-7

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