Journal of the Chemical Society. Chemical communications p. 1128 - 1130 (1988)
Update date:2022-08-05
Topics:
Baldwin, Jack E.
Norris, William J.
Freeman, Richard T.
Bradley, Mark
Adlington, Robert M.
et al.
Incubation of isopenicillin synthase (IPNS) with analogues of the natural substrate <(5S)-5-amino-carboxypentanoyl>-L-cysteinyl-D-valine (2) in which the cysteinyl residue was replaced by homocysteine gave epimeric 5-hydroxy γ-lactams (10), with no evidence for the formation of bicyclic products.
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