Efficient Synthesis of 2-Vinyl-γ-butyrolactones and 2-Vinyl-γ-butyrolactams by Palladium-Catalyzed Decarboxylative Carbonylation

DOI: 10.1246/bcsj.65.97

Source and publish data:

Bulletin of the Chemical Society of Japan p. 97 - 110 (1992)

Update date:2022-08-05

Topics: Synthesis Palladium Efficient Decarboxylative Carbonylation Vinyl Butyrolactone

Authors:

Bando, Takashi

Tanaka, Shuji

Fugami, Keigo

Yoshida, Zen-ichi

Tamaru, Yoshinao

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Article abstract of DOI:10.1246/bcsj.65.97

4-Vinyl-1,3-dioxan-2-ones (cyclic carbonates) undergo decarboxylation-carbonylation by the catalysis of Pd(0) species under CO (in most cases, 1 atm) to provide 2-vinyl-γ-butyrolactones in good yields.The course of the reaction of 6-vinyltetrahydro-2H-1,3

Full text of DOI:10.1246/bcsj.65.97

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