Bulletin of the Chemical Society of Japan p. 97 - 110 (1992)
Update date:2022-08-05
Topics: Synthesis Palladium Efficient Decarboxylative Carbonylation Vinyl Butyrolactone
Bando, Takashi
Tanaka, Shuji
Fugami, Keigo
Yoshida, Zen-ichi
Tamaru, Yoshinao
4-Vinyl-1,3-dioxan-2-ones (cyclic carbonates) undergo decarboxylation-carbonylation by the catalysis of Pd(0) species under CO (in most cases, 1 atm) to provide 2-vinyl-γ-butyrolactones in good yields.The course of the reaction of 6-vinyltetrahydro-2H-1,3
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