Chemistry Letters p. 1339 - 1342 (1988)
Update date:2022-08-05
Topics:
Tazaki, Masato
Nagahama, Shizuo
Takagi, Makoto
Clean ring cleavage of 1,2-dithiolane by carbanion was first recognized for 4,4-diethyl-1,2-dithiolane (3) in the reaction with Grignard reagents, the reactivity being attributed to the low polymerizing tendency of 3, similar to that of the enzyme-bound lipoic acid.
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