Chemistry Letters p. 219 - 222 (1988)
Update date:2022-08-02
Topics:
Hase, Toshiya
Miyashita, Akira
Nohira, Hiroyuki
M(PPh3)4 (M=Ni, Pd, Pt) promoted regioselective methylation of 1,2-epoxy-2-methylpropane with methyl iodide affording 2,2-dimethylpropanol.In the course of the reaction, trans-CH3MI(PPh3)2, initially formed from the reaction of M(PPh3)4 with CH3I, attacked the epoxide electrophilicly resulting regioselective cleavage of the C-O bond of the epoxide, followed by the formation of the isolable 2,2-dimethylpropoxymetal complexes.
View MoreBeijing Harmony Chemical Co., Ltd.
Contact:86-010-84956928
Address:Room 207, Jin feng he B building, No 8 Xin Jie Kou Wai Street, Xi Cheng District, Beijing,PRC. 10008
Tianjin Tongde Biological Technology Co., Ltd.
Contact:86-22-23309138
Address:Room 402, bulidingE3 Detection certification park, XiQingDistrict, Tianjin City
Jiangsu Allyrise Pharmaceutical Co., Ltd.(expird)
Contact:+86-523-86818997
Address:Taizhou,Jiangsu Province,CHINA
MTT Pharma & Bio-technology Co.,Ltd(expird)
Contact:+86-21-58407925
Address:Room2019, Building C, Tomson Center, No.158, Zhang Yang Road, Shanghai, China
website:http://www.eastarchem.com/
Contact:1-800-898-2436
Address:1215 K Street, STE 1700
Doi:10.3987/COM-13-S(S)41
(2014)Doi:10.1002/ejoc.201901330
(2019)Doi:10.1021/jm00038a012
(1994)Doi:10.1021/ja905988e
(2009)Doi:10.1021/ja905338x
(2009)Doi:10.1016/j.carres.2004.12.014
(2005)
