Chemistry Letters p. 219 - 222 (1988)
Update date:2022-08-02
Topics:
Hase, Toshiya
Miyashita, Akira
Nohira, Hiroyuki
M(PPh3)4 (M=Ni, Pd, Pt) promoted regioselective methylation of 1,2-epoxy-2-methylpropane with methyl iodide affording 2,2-dimethylpropanol.In the course of the reaction, trans-CH3MI(PPh3)2, initially formed from the reaction of M(PPh3)4 with CH3I, attacked the epoxide electrophilicly resulting regioselective cleavage of the C-O bond of the epoxide, followed by the formation of the isolable 2,2-dimethylpropoxymetal complexes.
View MoreHefei Highzone Fine Chemical S&T CO.,LTD
Contact:86-0551-63663560
Address:room 1801 NO. 24 Shuguang RD.
Contact:+86-15850770348
Address:51 OF XIANGFANGCUN ROAD, Nanjing 210002, China
Chengdu Green technology Co.,Ltd.
Contact:86-28-82608355
Address:C9 ,Economic Headquarters, Economic Development Zone, Chengdu.
Contact:+86-27-85733560
Address:NO.308,QINGNIAN RD.,WUHAN,CHINA
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)
Contact:+86-571-87046953
Address:No. 37, Qingchun Road
Doi:10.3987/COM-13-S(S)41
(2014)Doi:10.1002/ejoc.201901330
(2019)Doi:10.1021/jm00038a012
(1994)Doi:10.1021/ja905988e
(2009)Doi:10.1021/ja905338x
(2009)Doi:10.1016/j.carres.2004.12.014
(2005)
