Tetrahedron Letters p. 1713 - 1716 (1988)
Update date:2022-08-05
Topics:
Chardon, Catherine
Petit, Alain
Roux-Schmitt, Marie-Claude
Seyden-Penne, Jacqueline
The reaction of methyl 4-bromo-4-methylcrotonate 1 with anionic species α- to nitriles does not lead to cyclopropanes via a MIRC process.Products originating from a SN' reaction, 3 and 6, are predominantly formed from 2a-c, while products resulting from SN and SN' reactions are obtained in equimolar amounts from aminonitrile 2d.
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Doi:10.1021/jo9012282
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