REACTIVITY AND ELECTRONIC STRUCTURE OF A 4,5-DIDEHYDROPYRIMIDINE

DOI: 10.1016/S0040-4039(00)82018-3

Source and publish data:

Tetrahedron Letters p. 1687 - 1690 (1988)

Update date:2022-07-29

Topics: Reactivity Electronic structure Resonance Aromaticity

Authors:

Tielemans, Michel

Promel, Robert

Geerlings, Paul

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Article abstract of DOI:10.1016/S0040-4039(00)82018-3

The reaction of 2-t-butyl-4,5-didehydropyrimidine (2) with 1,3-dienes, two 1,3-dipoles (azides), an electrophile (iodine) and a nucleophile (ethanol) has been investigated.The results are correlated with the electronic structure of 4,5-didehydripyrimidine

Full text of DOI:10.1016/S0040-4039(00)82018-3

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