Oxidation of benzyl alcohols with difluoro(aryl)-λ3-bromane: formation of benzyl fluoromethyl ethers via oxidative rearrangement

DOI: 10.1016/j.tetlet.2009.06.042

Source and publish data:

Tetrahedron Letters p. 4792 - 4795 (2009)

Update date:2022-07-29

Topics: Oxidation Formation Benzyl Alcohols Oxidative rearrangement

Authors:

Ochiai, Masahito

Yoshimura, Akira

Miyamoto, Kazunori

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Article abstract of DOI:10.1016/j.tetlet.2009.06.042

Oxidative rearrangement of benzyl alcohols with difluoro(p-trifluoromethylphenyl)-λ³-bromane (5 × 10^-2 M) in chloroform at room temperature afforded aryl fluoromethyl ethers selectively in good yields, probably via 1,2-shift of aryl groups from benzylic carbon to oxygen atoms.

Full text of DOI:10.1016/j.tetlet.2009.06.042

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