Journal of Organic Chemistry p. 930 - 936 (1989)
Update date:2022-09-26
Topics:
Davies, Huw M. L.
McAfee, Melinda J.
Oldenburg, Claes E. M.
A stereoselective synthesis of a series of fused seven-membered carbocycles was achieved by a formal intramolecular 3 + 4 cycloaddition between vinylcarbenoids, generated by rhodium(II) acetate catalyzed decomposition of vinyldiazomethanes, and dienes.The products are formed by a tandem cyclopropanation/Cope rearrangement sequence rather than a concerted process.
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