Formation of the Novel Neopentylidenoborane Me3Si(t-Bu)N=B=CH(t-Bu) from the Tantalum Neopentylidene Complex by Metathesis

DOI: 10.1039/c39880000183

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 183 - 185 (1988)

Update date:2022-09-26

Topics:

Authors:

Manners, Ian

Paetzold, Peter

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880000183

The aminoiminoborane reacts with the alkylidene complex <(η-C5H5)Cl2Ta=CH(t-Bu)> at -50 deg C to give a (2 + 2) cycloadduct containing a ring; on warming to 0 deg C cleavage occurs, affording the metathesis products Me3Si(t-Bu)N=B=CH(t-Bu) and <(η-C5H5)Cl2Ta=N(t-Bu)>.

Full text of DOI:10.1039/c39880000183

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(CH₃)3Si(C₄H₉)NBC(H(C₄H₉))C((C₆H₅)2)O

Cas No:119097-41-5

R&D Labs maybe for 119097-41-5

Luna Chemicals Co.,Ltd.

Contact:+86-570-4336358

Address:No.87 Building,Tianqian,Sidu Town
zhengzhou Triz Pharma-Tech Co., Ltd

website:http://www.Trizpharma-tech.com

Contact:+86-0371-86597269，53392065

Address:High-tech Industrial Development Zone, Zhengzhou City, NO.7 Holly Street
Suzhou CarbonWell Pharma-Tech Co., Ltd

Contact:Tel: + 86 (0)512-8898-1216; + 86-18606258602

Address:2358 Changan Road, Wujiang Scientific Innovation Park, Wujiang, Jiangsu Province, P. R. China 215200
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD

Contact:86-21-60560171

Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
ALPHA PHARMACEUTICAL CO，LTD JIANGSU

Contact:+86-527-84829968,+86-527-84829998

Address:suqian city

Relevant to this article

Asymmetric transfer hydrogenation in aqueous media catalyzed by resin-supported peptide having a polyleucine tether

Doi:10.1016/j.tetasy.2009.02.036
(2009)
Supramolecular Aggregation of Perfluoroorganyl Iodane Reagents in the Solid State and in Solution

Doi:10.1002/ejoc.201800358
(2018)
Intramolecular diels-alder reactions in ruthenium vinylidene complexes containing anthracenyl groups

Doi:10.1021/om8011294
(2009)
Replacing alkyl sulfonamide with aromatic sulfonamide in sulfonamide-type RXR agonists favors switch towards antagonist activity

Doi:10.1016/j.bmcl.2008.11.086
(2009)
131. Synthesis of 2-Cycloalkenones (Parts of 1,4-Diacyl-1,3-butadiene Systems) and of a Heterocyclic Analogue by Metal-Catalyzed Decomposition of 2-Diazoacylfurans

Doi:10.1002/hlca.19870700524
(1987)
THE SYNTHESIS OF EITHER (+) OR (-) TRANS-2,5-DIMETHYLPYRROLIDINE

Doi:10.1016/S0040-4039(00)96049-0
(1987)

Article Doi