Stereochemical Control in Hex-5-enyl Radical Cyclizations: From Carbohydrates to Carbocycles. 3

DOI: 10.1021/ja00187a031

Source and publish data:

Journal of the American Chemical Society p. 1759 - 1769 (1989)

Update date:2022-08-04

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Authors:

RajanBabu, T. V.

Fukunaga, Tadamichi

Reddy, G. S.

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Article abstract of DOI:10.1021/ja00187a031

The hex-5-enyl radical cyclization reaction was applied to prepare highly oxygenated cyclopentanoids from aldopyranose sugars.The Wittig reaction of the sugars readily provides hex-5-en-1-ols which were converted to hex-5-enyl radicals via one of the vari

Full text of DOI:10.1021/ja00187a031

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