Stereochemical Control in Hex-5-enyl Radical Cyclizations: From Carbohydrates to Carbocycles. 3

DOI: 10.1021/ja00187a031

Source and publish data:

Journal of the American Chemical Society p. 1759 - 1769 (1989)

Update date:2022-08-04

Topics:

Authors:

RajanBabu, T. V.

Fukunaga, Tadamichi

Reddy, G. S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00187a031

The hex-5-enyl radical cyclization reaction was applied to prepare highly oxygenated cyclopentanoids from aldopyranose sugars.The Wittig reaction of the sugars readily provides hex-5-en-1-ols which were converted to hex-5-enyl radicals via one of the vari

Full text of DOI:10.1021/ja00187a031

Products guided by the article

Product name:(2R,4aR,8R,8aS)-6-Allyloxy-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine

Cas No:119111-21-6

R&D Labs maybe for 119111-21-6

Chengdu CSH Pharmaceutical Co.,ltd

Contact:+86-(28)-85321971

Address:Block B,New Hope Int. Tian Fu New District, Chengdu, Sichuan, China
Chengdu Shengnuo Biological Technology Co., Ltd.

Contact:86-028-85275045

Address:Sichuan Province Chengdu hi tech Zone Tianfu Avenue North of 1480
Hebei Think-Do Environment Co., Ltd

website:http://www.thinkdo-environment.com

Contact:0311-86510809-

Address:No 6, Shilian Middle Street, Circular Chemical Industry Park
Wuhan Hanye Chemical New Material Co.,Ltd

Contact:+86-27-85308141

Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China

Relevant to this article

(2-Arylhydrazonomethyl)-substituted xanthones as antimycotics: Synthesis and fungistatic activity against Candida species

Doi:10.1016/S0223-5234(01)01332-0
(2002)
Syntheses and remarkable photophysical properties of 5-(2-pyridyl) pyrazolate boron complexes; photoinduced electron transfer

Doi:10.1039/b309374c
(2003)
N-Bromosuccinimide-Mediated Synthesis of Substituted Quinoxalines

Doi:10.1055/s-0035-1561472
(2016)
3,5-Bis(3′-indolyl)pyrazoles, analogues of marine alkaloid nortopsentin: Synthesis and antitumor properties

Doi:10.1016/j.bmcl.2007.09.042
(2007)
Allylic Phosphorus Ylides Directly Generated from Alcohols with Water as the only Byproduct

Doi:10.1021/acs.orglett.9b01349
(2019)
Absolute configuration of the four stereoisomers of valnoctamide (2- ethyl-3-methyl valeramide), a potentially new stereospecific antiepileptic and CNS drug

Doi:10.1016/S0957-4166(99)00047-6
(1999)

Article Doi