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ARTICLE
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that on the surface of S3 residue the bumps and particles
appear as a thermally insulating and oxidatively stable sili-
con oxycarbide surface char.41
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CONCLUSIONS
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2008, 24, 5766–5772.
Well-defined POSS-based fluoroether-containing terpolymer
were prepared, characterized, and applied to the cotton fabric
as water and oil repellent. The POSS content influences the
thermal stability, solubility as well as the structure of the ter-
polymer. The thermal stability of the terpolymer was improved
by POSS incorporation. The structure of the terpolymer with
low POSS content is probably to be star-shaped and thus the
terpolymer has good solubility. The terpolymer with excessive
POSS becomes insoluble due to its crosslinked network struc-
ture. More importantly, the hydrophobicity/oleophobicity and
the flammability of the coated cotton fabrics also are influ-
enced by the POSS content. When 7.1 wt % POSS incorporated
in the resulting terpolymer, the coated cotton fabric shows
superhydrophobicity and high oleophobicity. In addition, the
terpolymer is potential to be endowed other functional groups
from the unreacted vinyl groups in the POSS segments, and
thus to be developed for various potential applications.
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The National Natural Science Foundation of China
(No.21072028) and Shanghai Municipal Scientific Committee
(09PJ1400800) are greatly acknowledged for funding this
work.
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