ACCESS TO THE SYNTHESIS OF WYBUTOSINE, THE FIRST TRICYCLIC FLUORESCENT NUCLEOSIDE ISOLATED FROM PHENYLALANINE TRANSFER RIBONUCLEIC ACIDS

DOI: 10.1016/S0040-4039(00)80435-9

Source and publish data:

Tetrahedron Letters p. 4129 - 4132 (1988)

Update date:2022-07-30

Topics:

Authors:

Itaya, Taisuke

Shimomichi, Manabu

Ozasa, Masako

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Article abstract of DOI:10.1016/S0040-4039(00)80435-9

An improved synthesis of the key intermediate 5 for the chiral syntheses of wybutine (1c) and hydroxywybutine (1d) has been achieved by palladium-catalyzed vinylation, which has been utilized for the first synthesis of 3-β-D-ribofuranosylwybutine (2c).

Full text of DOI:10.1016/S0040-4039(00)80435-9

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