DIASTEREOTOPIC SELECTION OF C2 HYDROGENS IN THE REARRANGEMENT OF C1-SUBSTITUTED EPOXIDES: AN EXAMINATION OF STYRENE OXIDE

DOI: 10.1016/S0040-4039(00)86115-8

Source and publish data:

Tetrahedron Letters p. 2575 - 2576 (1988)

Update date:2022-08-02

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Authors:

Coxon, J. M.

McDonald, D. Q.

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Article abstract of DOI:10.1016/S0040-4039(00)86115-8

Rearrangement of styrene oxide with (a) LiClO4 and (b) BF3 to give phenylethanal exhibits diastereotopic selection with migration of the hydrogen trans to the phenyl group being favoured 1.4 and 1.14 times respectively.The rate of rotation about the C1-C2

Full text of DOI:10.1016/S0040-4039(00)86115-8

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