ACYLATION OF 1,3-BIS(TRIMETHYLSILYL)-PROPENE AND 1,8-BIS(TRIMETHYLSILYL)-1,7-OCTADIENE. OBTENTION OF (+/-)-1-ALKYL-2,5-DIVINYLCYCLOPENTANOLS.

DOI: 10.1016/S0040-4020(01)86649-7

Source and publish data:

Tetrahedron p. 3975 - 3982 (1988)

Update date:2022-09-26

Topics:

Authors:

Tubul, A.

Santelli, M.

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Article abstract of DOI:10.1016/S0040-4020(01)86649-7

The addition of α,β-ethylenic acyl chlorides to 1,3-bis(trimethylsilyl)-propene 1 leads to propenyl-alkenyl ketones 7, while addition of acyl chlorides with 1,8-bis(trimethylsilyl)-1,7-octadiene 2 gives 1-alkyl-2,5-divinylcyclopentanols 10 and 1-acyl-2-trimethylsilylmethyl-3-vinylcyclopentanes 12 and 13.

Full text of DOI:10.1016/S0040-4020(01)86649-7

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