Stereocontrol in intermolecular nucleophilic addition to N-acyliminium ion directed by a bicyclo[2.2.1]heptene or 7-oxabicyclo[2.2.1]heptene group. A novel route to 5-substituted 3-pyrrolin-2-ones of high optical purity

DOI: 10.1248/cpb.40.1670

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1670 - 1672 (1992)

Update date:2022-08-05

Topics:

Authors:

Arai Arai

Fujii Fujii

Ohno Ohno

Koizumi Koizumi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.40.1670

Intermolecular nucleophilic additions to the conformationally rigid, tricyclic pyrrolidinium ion (derived from 2 or 6) took place exclusively from the less-hindered face fused with its bicyclo[2.2.1]heptene or 7-oxobicyclo-[2.2.1]heptene moiety. Retro-Die

Full text of DOI:10.1248/cpb.40.1670

NII-Electronic Library Service

Products guided by the article

Product name:(S)-5-Heptyl-1-phenyl-pyrrolidin-2-one

Cas No:119690-98-1

R&D Labs maybe for 119690-98-1

Anhui Charm Imp.&Exp.Co., Ltd

website:http://www.chinacharm.cn/

Contact:86 551 5316260

Address:No. 211,XiangZhang Road,Hefei City,Anhui Province,China
Beijing Stable Chemcial Co.ltd

Contact:86-10-63785052

Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China
Chengdu Pukang Biotechnology Co., Ltd

Contact:+86-28-82550498

Address:No. 558 Rulin Road,Xinjin county,Chengdu city, China
GUANGZHOU MEDCAN PHARMATECH LTD

website:http://www.gzmedcan.com

Contact:+86-20-82519649

Address:Building J,Room 101,1 JiangtashanRd,Guang Zhou Science City,Guang Zhou ,China
Fuxin Jintelai Fluorin Chemical Co., Ltd.

Contact:+86-0418-8229599

Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China

Relevant to this article

Synthesis of nicotine and diverse analogues using intramolecular [3+2] cycloaddition

Doi:10.1055/s-0029-1217746
(2009)
REACTIVITY OF PHENYLIODONIUM BIS(ARYLSULPHONYL)METHYLIDES TOWARDS ALKENES AND ALKYNES: CRYSTAL STRUCTURE OF 9-PHENYLSULPHONYL-1,2,3,4,4a,9a-HEXAHYDRO-1,4-METHANOFLUORENE

Doi:10.1039/P19880002839
(1988)
Optimization of a Novel Quinazolinone-Based Series of Transient Receptor Potential A1 (TRPA1) Antagonists Demonstrating Potent in Vivo Activity

Doi:10.1021/acs.jmedchem.6b00039
(2016)
Reactions of 4-unsubstituted 4,5-dihydro-1H-indeno[1,2-b]pyridines

Doi:10.1007/s10593-009-0270-2
(2009)
Perylenequinone natural products: Enantioselective synthesis of the oxidized pentacyclic core

Doi:10.1021/jo9013832
(2010)
Straightforward synthesis of protected 2-hydroxyglycals by chlorination-dehydrochlorination of carbohydrate hemiacetals

Doi:10.1016/j.carres.2020.108086
(2020)

Article Doi