Allene Epoxidation. Highly Functionalized Tetrahydrofurans and Tetrahydropyrans from the Oxidative Cyclization of Allenic Alcohols

DOI: 10.1016/S0040-4020(01)92232-X

Source and publish data:

Tetrahedron p. 1427 - 1448 (1992)

Update date:2022-08-03

Topics:

Authors:

Crandall, Jack K.

Batal, David J.

Lin, Feng

Reix, Thierry

Nadol, Gregory S.

Ng, Raymond A.

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Article abstract of DOI:10.1016/S0040-4020(01)92232-X

The dimethyldioxirane oxidation of various allenic alcohols yields highly functionalized tetrahydrofuran and tetrahydropyran derivatives via intramolecular nucleophilic addition of the hydroxy group to an intermediate allene diepoxide.

Full text of DOI:10.1016/S0040-4020(01)92232-X

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