Aromaten(phosphan)metall-Komplexe; XIII. Osmium(II)- und Osmium(0)-Komplexe mit p-Cymen als aromatischem Liganden

Article abstract of DOI:10.1016/0022-328X(88)80244-4

An improved synthesis of <(p-Cym)OsCl2>2 (1) using OsCl3.3H2O as the starting material is described. 1 reacts with PMe3, PPh3 and CO by Cl bridge cleavage to give (p-Cym)OsCl2(L) (2-4).Replacement of the chloride ligands in 1 and 2 (L = PMe3) by iodide le