Aromaten(phosphan)metall-Komplexe; XIII. Osmium(II)- und Osmium(0)-Komplexe mit p-Cymen als aromatischem Liganden

DOI: 10.1016/0022-328X(88)80244-4

Source and publish data:

Journal of Organometallic Chemistry p. 151 - 166 (1988)

Update date:2022-08-04

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Authors:

Werner, H.

Zenkert, K.

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Article abstract of DOI:10.1016/0022-328X(88)80244-4

An improved synthesis of <(p-Cym)OsCl2>2 (1) using OsCl3.3H2O as the starting material is described. 1 reacts with PMe3, PPh3 and CO by Cl bridge cleavage to give (p-Cym)OsCl2(L) (2-4).Replacement of the chloride ligands in 1 and 2 (L = PMe3) by iodide le

Full text of DOI:10.1016/0022-328X(88)80244-4

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