The Application of Difunctional Organosilicon Compounds to Organic Synthesis; 1,3-Asymmetric Induction in the Reduction of β-Hydroxy-ketones

DOI: 10.1039/c39860000831

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 831 - 832 (1986)

Update date:2022-08-04

Topics:

Authors:

Anwar, Saeed

Davis, Anthony P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39860000831

A number of β-hydroxy-ketones were reduced to anti-1,3-diols with diastereoisomeric excesses exceeding 95percent, by a method involving presumed intramolecular transfer of hydrogen from a silicon atom to the carbonyl carbon.

Full text of DOI:10.1039/c39860000831

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:trans-2,2,4-tri-isopropyl-6-methyl-1,3-dioxa-2-silacyclohexane

Cas No:119968-56-8

R&D Labs maybe for 119968-56-8

STAR SYNTHESIS CO.,LIMITED

Contact:+(852) 301-98033

Address:Flat C, 23/F, Lucky Plaza, 315-321 Lockhart Road, Wan Chai, Hong Kong
Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong
Angelisun(Chongqing) Pharmaceutical Co., LTD.

Contact:+86-23-68030926-816

Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA
Nanjing Habo Medical Technology Co., Ltd.

Contact:025－85769882

Address:No.108. Ganjiabian east. Qixia District .Nanjing

Relevant to this article

Dimetallic Palladium-NHC Complexes: Synthesis, Characterization, and Catalytic Application for Direct C?H Arylation Reaction of Heteroaromatics with Aryl Chlorides

Doi:10.1002/adsc.201901189
(2020)
From NHC→germylenes to stable NHC→germanone complexes

Doi:10.1039/b914060c
(2009)
Radical addition of ethers to terminal alkynes with high E-selectivity

Doi:10.1002/ejoc.200900858
(2009)
ASYMMETRIC SYNTHESIS OF α-AMINO ACIDS BY ALKYLATION OF N--2,5-BIS(METHOXYMETHOXYMETHYL)PYRROLIDINE AND ENANTIOSELECTIVE SYNTHESIS OF PROTECTED (2S,9S)-2-AMINO-8-OXO-9,10-EPOXYDECANOIC ACID

Doi:10.1016/S0040-4020(01)86040-3
(1988)
Enantioselective Friedel-Crafts alkylation of 4,7-dihydroindoles with enones catalyzed by primary-secondary diamines

Doi:10.1002/chem.200901635
(2009)
Investigation of the effect of amino acid chirality in the internucleoside linker on DNA:DNA and DNA:RNA duplex stability

Doi:10.1016/j.tet.2015.02.042
(2015)

Article Doi