The Application of Difunctional Organosilicon Compounds to Organic Synthesis; 1,3-Asymmetric Induction in the Reduction of β-Hydroxy-ketones

DOI: 10.1039/c39860000831

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 831 - 832 (1986)

Update date:2022-08-04

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Authors:

Anwar, Saeed

Davis, Anthony P.

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Article abstract of DOI:10.1039/c39860000831

A number of β-hydroxy-ketones were reduced to anti-1,3-diols with diastereoisomeric excesses exceeding 95percent, by a method involving presumed intramolecular transfer of hydrogen from a silicon atom to the carbonyl carbon.

Full text of DOI:10.1039/c39860000831

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