α-Methoxyketone Synthesis via Ketone Homologation: ZrCl4-Mediated Hydroxy Sulfone Rearrangements

DOI: 10.1039/c39940002289

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2289 - 2290 (1994)

Update date:2022-09-26

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Authors:

Montana, John G.

Phillipson, Neil

Taylor, Richard J. K.

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Article abstract of DOI:10.1039/c39940002289

The adducts between ketones and the anion derived from <(methoxymethyl)sulfonyl>benzene undergo efficient, regioselective rearrangement to give α-methoxyketones when treated with ZrCl4 and HfCl4; this new procedure allows the sulfone-mediated homologation

Full text of DOI:10.1039/c39940002289

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