α-Methoxyketone Synthesis via Ketone Homologation: ZrCl4-Mediated Hydroxy Sulfone Rearrangements

DOI: 10.1039/c39940002289

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2289 - 2290 (1994)

Update date:2022-09-26

Topics:

Authors:

Montana, John G.

Phillipson, Neil

Taylor, Richard J. K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39940002289

The adducts between ketones and the anion derived from <(methoxymethyl)sulfonyl>benzene undergo efficient, regioselective rearrangement to give α-methoxyketones when treated with ZrCl4 and HfCl4; this new procedure allows the sulfone-mediated homologation

Full text of DOI:10.1039/c39940002289

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-methoxy-1-(2-methylphenyl)propan-2-one

Cas No:1200-98-2

R&D Labs maybe for 1200-98-2

Yingkou Sanzheng Organic Chemical Co. Ltd.

Contact:+86-417-3638818

Address:25 Gengxinli Village, Daqing Road, Yingkou, Liaoning, China
Hebei Kangtai Pharmaceutical Co.,Ltd

Contact:+86-0317-3512963

Address:Wugang Road,Mengcun of Cangzhou City,Hebei Province ,China
A.M FOOD CHEMICAL CO., LIMITED

Contact:86-531-87100375

Address:20Floor，Bblock，1Building，pharma-valley，Jinan，China
Wuhan Better Organic Technology Inc.

Contact:13307163183

Address:Wuhan Economic&Technology Development Zone, Hubei
Huayi Isotopes Co.

Contact:+ 86 512 52491118

Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China

Relevant to this article

Use of 2-phenylsulphonyl cyclic ethers in the preparation of tetrahydropyran and tetrahydrofuran acetals and in some glycosidation reactions

Doi:10.1016/S0040-4020(01)86389-4
(1991)
Pd(OAc)₂/DABCO as an efficient and phosphine-free catalytic system for the synthesis of single and double Weinreb amides by the aminocarbonylation of aryl iodides

Doi:10.1039/c4ob00729h
(2014)
Synthesis and conformational studies of 9-methoxy- and 9-methyl- 2,11-dithia[3.3]metacyclophanes

Doi:10.3184/030823409X12474221035244
(2009)
Synthesis and mesomorphic behavior of novel calamitic liquid crystalline dimesogens possessing a cholesteryl moiety connected to a pyrimidine core

Doi:10.1080/15421406.2013.779180
(2013)
Complexation and C-H/C-P bond activation of the (PPh₂)C ₆₀H molecule on triosmium carbonyl clusters

Doi:10.1021/om900914a
(2010)
Synthesis, structure, and reactivity of group 14 bid (thiophosphinoyl) metal complexes

Doi:10.1021/om9008923
(2010)

Article Doi