Action of Alkali on O-Benzylated Aldoses: A Simple Rationalization of Some Reactions Occurring in Alkaline Media

DOI: 10.1021/jo00009a024

Source and publish data:

Journal of Organic Chemistry p. 3054 - 3058 (1991)

Update date:2022-08-04

Topics: Reactions Hydrolysis alkali Nucleophilic Attack Saponification

Authors:

Anastasia, Mario

Allevi, Pietro

Ciuffreda, Pierangela

Fiecchi, Alberto

Scala, Antonio

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Article abstract of DOI:10.1021/jo00009a024

Treatment of some O-benzyl-protected aldopyranoses and aldofuranoses with sodium 2-propoxide or K2CO3 brought about their equilibration and the loss of the elements of benzyl alcohol, with concomitant formation of a Z aldehyde.The latter rearranged rapidl

Full text of DOI:10.1021/jo00009a024

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