Tetrahedron Letters p. 5181 - 5184 (1988)
Update date:2022-08-02
Nokami, Junzo
Ogawa, Hideki
Miyamoto, Shinya
Mandai, Tadakatsu
Wakabayahi, Shoji
Tsuji, Jiro
3-substituted 1-alken-4-ols were oxidized with PdCl2-benzoquinone regioselectively at the terminal carbon to afford cyclic hemiacetals (γ-butyroacetols), which were converted to γ-butiroacetones by the Jones oxidation.This reactions was applied to the synthesis of optically active deoxyribose and γ-butenolides.
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